Direct observation of the radial breathing mode in CdSe nanorods.
نویسندگان
چکیده
We experimentally confirm the existence of the radial breathing mode in CdSe nanorods by Raman spectroscopy, which was deduced from ab initio calculations of the vibrational properties of bare CdSe nanowires and CdSe/ZnS core-shell nanowires. We calculated the modes' frequency for various diameters and measured a set of bare CdSe nanorods and CdSe/ZnS core-shell nanorods to determine the diameter dependence of the modes' frequency. The frequency of this mode is strongly diameter dependent and it can be used to estimate the nanorod diameter from a Raman measurement alone.
منابع مشابه
Validation of Shell Theory for Modeling the Radial Breathing Mode of a Single-Walled Carbon Nanotube (RESEARCH NOTE)
In this paper, the radial breathing mode (RBM) frequency of single-walled carbon nanotube (SWCNT) is studied based on the thin shell theory. For this purpose, SWCNT is considered as an elastic thin cylindrical shell. The dynamic equation of RBM is derived using the Hamilton’s principle. An analytical solution of the RBM frequency of SWCNT is obtained. The advantage of this formulation is that i...
متن کاملRadial Breathing Mode Frequency of Multi-Walled Carbon Nanotube Via Multiple-Elastic Thin Shell Theory
In this paper, the radial breathing mode (RBM) frequencies of multi-walled carbon nanotubes (MWCNTs) are obtained based on the multiple-elastic thin shell model. For this purpose, MWCNT is considered as a multiple concentric elastic thin cylindrical shells, which are coupled through van der Waals (vdW) forces between two adjacent tubes. Lennard-Jones potential is used to calculate the vdW ...
متن کاملDislocation-driven growth of porous CdSe nanorods from CdSe·(ethylenediamine)(0.5) nanorods.
Porous CdSe nanorods having a novel flute-like morphology have been prepared facilely via the hydrothermal treatment of CdSe·(en)0.5 (en = ethylenediamine) nanorods as sacrificial templates. During the hydrothermal process, various crystalline imperfections such as stacking faults and twinning planes appear due to lattice mismatches between orthorhombic CdSe·(en)0.5 and hexagonal wurtzite porou...
متن کاملUltrafast dynamics and single particle spectroscopy of Au-CdSe nanorods.
Time-resolved photoluminescence (PL) and transient absorption (TA) spectroscopy are conducted in order to get knowledge on the excited state of CdSe nanorods (NR), and to assess the impact of Au nanoparticles (NP) on the carrier dynamics of hybrid Au-CdSe NRs. The decay dynamics measured in solution show an increase of non-radiative decay channels in the presence of Au NPs, whose characteristic...
متن کاملOptical characterization of type-II CdTe/CdSe/CdTe heterostructure nanorods
The optical characteristics of an indirect type II transition in a series of size and shape-controlled linear CdTe/CdSe/CdTe heterostructure nanorods was studied by steady state and time resolved photoluminescence spectra. The energy and lifetime of the photoluminescence from the charge-separated band structure can be tuned by the band edges of the nanorods. Our results show a size-dependent tr...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Nano letters
دوره 8 12 شماره
صفحات -
تاریخ انتشار 2008